250ml = 0,25l

\(n_{H2SO4}=1,5.0,25=0,375\left(mol\right)\)

\(n_{Na2SO3}=\dfrac{37,8}{126}=0,3\left(mol\right)\)

a) Pt : \(H_2SO_4+Na_2SO_3\rightarrow Na_2SO_4+SO_2+H_2O|\)

                1              1                 1              1          1

              0,375        0,3             0,3            0,3

b) Lập tỉ số so sánh : \(\dfrac{0,375}{1}>\dfrac{0,3}{1}\)

                     ⇒ H₂SO₄ dư , Na₂SO₃ phản ứng hết

                     ⇒ Tính toán dựa vào số mol của Na₂SO₃

\(n_{SO2}=\dfrac{0,3.1}{1}=0,3\left(mol\right)\)

\(V_{SO2\left(dktc\right)}=0,3.22,4=6,72\left(l\right)\)

c) \(n_{Na2SO4}=\dfrac{0,3.1}{1}=0,3\left(mol\right)\)

\(n_{H2SO4\left(dư\right)}=0,375-0,3=0,075\left(mol\right)\)

\(C_{M_{Na2SO4}}=\dfrac{0,3}{0,25}=1,2\left(M\right)\)

\(C_{M_{H2SO4\left(dư\right)}}=\dfrac{0,075}{0,25}=0,3\left(M\right)\)

 Chúc bạn học tốt

1:

a) \(n_{Zn}=\dfrac{13}{65}=0,2\left(mol\right)\)

PTHH: \(Zn+H_2SO_4\rightarrow ZnSO_4+H_2\uparrow\)

______0,2------>0,2------------------->0,2_____(mol)

=> \(V_{H_2}=0,2.22,4=4,48\left(l\right)\)

b) \(V_{ddH_2SO_4}=\dfrac{0,2}{1}=0,2\left(l\right)\)

2:

a) 

\(n_{HCl}=2.0,2=0,4\left(mol\right)\)

PTHH: \(Mg+2HCl\rightarrow MgCl_2+H_2\uparrow\)

______0,2<------0,4------------------>0,2______(mol)

=> \(m_{Mg}=0,2.24=4,8\left(g\right)\)

b) \(V_{H_2}=0,2.22,4=4,48\left(l\right)\)

a, PT: \(Fe+2HCl\rightarrow FeCl_2+H_2\)

Ta có: \(n_{Fe}=\dfrac{11,2}{56}=0,2\left(mol\right)\)

\(n_{HCl}=0,5.1=0,5\left(mol\right)\)

Xét tỉ lệ: \(\dfrac{0,2}{1}< \dfrac{0,5}{2}\), ta được HCl dư.

Theo PT: \(\left\{{}\begin{matrix}n_{FeCl_2}=n_{H_2}=n_{Fe}=0,2\left(mol\right)\\n_{HCl\left(pư\right)}=2n_{Fe}=0,4\left(mol\right)\Rightarrow n_{HCl\left(dư\right)}=0,1\left(mol\right)\end{matrix}\right.\)

b, Dung dịch a gồm HCl dư và FeCl₂.

PT: \(HCl+NaOH\rightarrow NaCl+H_2O\)

\(FeCl_2+2NaOH\rightarrow Fe\left(OH\right)_{2\downarrow}+2NaCl\)

Theo PT: \(n_{NaOH}=n_{HCl\left(dư\right)}+2n_{FeCl_2}=0,5\left(mol\right)\)

\(\Rightarrow a=C_{M_{NaOH}}=\dfrac{0,5}{0,2}=2,5M\)

c, \(V_{H_2}=0,2.22,4=4,48\left(l\right)\)

Bạn tham khảo nhé!

\(a)H_2SO_4+Ba\left(NO_3\right)_2\rightarrow BaSO_4+2HNO_3\\ n_{H_2SO_4}=0,2.1=0,2l\\ n_{Ba\left(NO_3\right)_2}=n_{H_2SO_4}=0,2mol\\ m_{ddBa\left(NO_3\right)_2}=\dfrac{0,2.261}{20}\cdot100=261g\\ V_{ddBa\left(NO_3\right)_2}=\dfrac{261}{1,22}\approx213,9ml\\ c)n_{HNO_3}=0,2.4=0,4mol\\ C_{M_{HNO_3}}=\dfrac{0,4}{0,2+0,2139}\approx0,97M\)

nCuSO4=0,01 mol
Fe+CuSO4=> FeSO4+Cu
        0,01 mol          =>0,01 mol
mCu=0,01.64=0,64gam
FeSO4+2NaOH=>Fe(OH)2 +Na2SO4
0,01 mol=>0,02 mol
Vdd NaOH=0,02/1=0,02 lit

\(n_{KOH}=0.1\cdot1=0.1\left(mol\right)\)

\(n_{HCl}=0.1\cdot0.5=0.05\left(mol\right)\)

\(KOH+HCl\rightarrow KCl+H_2O\)

\(0.05.......0.05.......0.05\)

Dung dịch D : 0.05 (mol) KOH , 0.05 (mol) KCl

\(\left[K^+\right]=\dfrac{0.05+0.05}{0.1+0.1}=0.5\left(M\right)\)

\(\left[Cl^-\right]=\dfrac{0.05}{0.2}=0.25\left(M\right)\)

\(\left[OH^-\right]=\dfrac{0.05}{0.2}=0.25\left(M\right)\)

\(2KOH+H_2SO_4\rightarrow K_2SO_4+2H_2O\)

\(0.05.........0.025\)

\(V_{dd_{H_2SO_4}}=\dfrac{0.025}{1}=0.025\left(l\right)\)

\(a.H_2SO_{\text{4}}+2NaOH\rightarrow Na_2SO_4+2H_2O\left(1\right)\\ H_2SO_4+Fe\rightarrow FeSO_4+H_2\left(2\right)\\ n_{Fe}=\dfrac{19,04}{56}=0,34\left(mol\right)\\ n_{H_2}=n_{Fe}=0,34\left(mol\right)\\ \Rightarrow V_{H_2}=0,34.22,4=7,616\left(mol\right)\\ b.n_{H_2SO_4\left(2\right)}=n_{Fe}=0,34\left(mol\right)\\ n_{H_2SO_4\left(bđ\right)}=0,5.1=0,5\left(mol\right)\\ \Rightarrow n_{H_2SO_4\left(1\right)}=0,5-0,34=0,16\left(mol\right)\\ Tacó:n_{NaOH}=2n_{H_2SO_4 }=0,32\left(mol\right)\\ \Rightarrow V_{NaOH}=\dfrac{0,32}{0,5}=0,64\left(l\right)\)

a) \(n_{NaOH}=0,2.1=0,2\left(mol\right)\); \(n_{HNO_3}=0,2.0,5=0,1\left(mol\right)\)

\(NaOH+HNO_3\rightarrow NaNO_3+H_2O\)

0,2.............0,1

Lập tỉ lệ : \(\dfrac{0,2}{1}>\dfrac{0,1}{1}\) => Sau phản ứng NaOH dư

Dung dịch D gồm NaNO3 và NaOH dư

\(n_{NaNO_3}=n_{HNO_3}=0,1\left(mol\right)\)

\(n_{NaOH\left(pứ\right)}=n_{HNO_3}=0,1\left(mol\right)\)

\(n_{NaOH\left(dư\right)}=0,2-0,1=0,1\left(mol\right)\)

Ion trong dung dịch D : Na+ , NO3-, OH-

\(\left[Na^+\right]=\dfrac{0,1+0,1}{0,2}=1M\)

\(\left[NO_3^-\right]=\dfrac{0,1}{0,2}=0,5M\)

\(\left[OH^-\right]=\dfrac{0,1}{0,2}=0,5M\)

b)Trong dung dịch D chỉ có NaOH dư phản ứng

 \(2NaOH+H_2SO_4\rightarrow Na_2SO_4+H_2O\)

0,1................0,05

=> \(V_{H_2SO_4}=\dfrac{0,05}{1}=0,05\left(l\right)\)

Tách ra lần bài đi em !

\(n_{KOH}=0.1\cdot1=0.1\left(mol\right)\)

\(n_{H_2SO_4}=0.3\cdot0.5=0.15\left(mol\right)\)

\(2KOH+H_2SO_4\rightarrow K_2SO_4+H_2O\)

\(0.1..........0.05...............0.05\)

Dung dịch D : 0.05 (mol) K₂SO₄ , 0.1 (mol) H₂SO₄

\(\left[K^+\right]=\dfrac{0.05\cdot2}{0.1+0.3}=0.25\left(M\right)\)

\(\left[H^+\right]=\dfrac{0.1\cdot2}{0.1+0.3}=0.5\left(M\right)\)

\(\left[SO_4^{2-}\right]=\dfrac{0.05+0.1}{0.1+0.3}=0.375\left(M\right)\)

\(2NaOH+H_2SO_4\rightarrow K_2SO_4+H_2O\)

\(0.2..................0.1\)

\(V_{dd_{NaOH}}=\dfrac{0.2}{1}=0.2\left(l\right)\)